Preheat the oven to 350 degrees. Once the babka has risen, bake it for 40 to 45 minutes until deeply burned. When you tap on the surface of the bread, it should sound hollow. Remove from pan and set aside.
Meanwhile, prepare the glaze: In a medium heatproof bowl set over a pot of simmering water, melt the chocolate and butter and stir until smooth. Stir in corn syrup, espresso powder, vanilla paste and salt and remove from heat.
Pour the warm chocolate glaze over the entire surface of the babka(s). This will keep your babka nice and moist and add another layer of flavor. Let cool until firm, about 30 minutes. You'll know it's cured when the appearance goes from shiny to more opaque. Slice and serve.
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